As far as the actual chain pitch, the tips of the teeth are the same spacing as the center of the roller grooves. If you took a couple of dowel pins the size of the rollers, you could measure over a pair of them in adjacent grooves and establish the chain pitch. Since the links, when viewed individually are held in a straight, static distance by the side plates, subtracting one diameter from the "over the pins" dimension would yield the chain pitch. Their are only a few standards, so even an estimate with a pair of dial calipers compared to a chart would get you the chain ID.
Am I correct that the chain pitch (or chain #) is what you are needing? Oh, and yes, the roller pretty well seats in the bottom of the groove, until the pull side of the groove begins to wear, and then it has a tendency to climb up, and eventually out of the groove.