I agree. The dissimilar metals voltage, even if it were a very significant big voltage, connects both metals to a journey through copper, and then goes through another soldering of the same metals, completely cancelling itself if the temperature at both ends is the same. They are all on the same board, and there is no raging dissipation to make one end way hotter than the other.Thing is, even if it looks like it wouldn't take much of a gradient to get a 500uv difference between 6.5mv/K and 4mv/K, the interfaces are VERY close together -- think IC pin to solder, then the same solder pool to the copper PCB trace right underneath it. Not much separation, physically and thermally speaking. So while some offset is theoretically possible, I don't think that is what is going on here.
The voltage is tiny to begin with, even before it cancels. If the temperatures both ends are equal, then I think offset is not even theoretically possible!
This time, I would say thermocouple voltages are unlikely to be the cause.