If the probability of a failure was 1/1.000, the probability of two independent relays both failing is 1/1,000,000. However a double pole relay isn't the same as two independent relays as one set of contacts welding would in all likelihood keep the second set closed as well.
But I will often wire two sets of contacts in parallel on a double pole relay or switch as it increases the reliability of obtaining a contact close . In that mode, the contacts are functioning as independents and the probability of no having a closure is as above so the respective probabilities of having a closure is 999/1,000 vs 999,999/1/000,000 for one set vs two sets of contacts.