Based on the tooling you already have, I'd do it like Flying suggested above. If the stock is long, clamp it in the V-block horizontally and do two sides. Then rotate the V-block 90 deg. without unclamping the rod from the block and do the other two sides. That'll leave you with your cutter's radius at the bottom of the cuts. If you need a squared interface to the rod, do the same set up, but remove material off the top surface. Then rotate the block 90 deg. and repeat until you have a square.
Like mentioned above, many ways to do the task if you have the tooling available. Most of us are always looking for excuses to buy more tooling. I think I have more collets than Carter's has little pills. I generally square rod stock using a square collet block and 5-C collets. The width of the block is written on my block with a paint marker so I know the delta from the vise jaws if I'm cutting on the sides. I've also used a spin indexer with 5-C collets, a dividing head and the V-block method mentioned in this post.
Bruce
Like mentioned above, many ways to do the task if you have the tooling available. Most of us are always looking for excuses to buy more tooling. I think I have more collets than Carter's has little pills. I generally square rod stock using a square collet block and 5-C collets. The width of the block is written on my block with a paint marker so I know the delta from the vise jaws if I'm cutting on the sides. I've also used a spin indexer with 5-C collets, a dividing head and the V-block method mentioned in this post.
Bruce