I think the galvanizing would be better, But they cannot galvanize, or powder coat the threads for the drain valve, so there will always be a place for rust to start. Thats why I add some oil to the line going into the tank every month or so. Except maybe for tires, there is nothing that I use the air for that the oil will hurt.
The coolest setup I have seen, and what I will someday copy. A truck maintenance shop in Pa, had two compressors, each fed into its own 15 or so gal tank, which then fed into a large 50 gal tank. Had a setup so that each compressor alternated which one started each time, and if the air dropped enough, both kicked in. From each compressor to the small tank, was over 10 feet or so of pipe, which he had wire wrapped around, to help it shed off some heat. most of the moisture settled out in the pipe, and small tanks.