"Black iron", high carbon iron, hasn't been used for pipe for many, many years. What today is called "black iron" is basically cast steel that has not been galvanized. It seems (natural) gas reacts with the zinc in galvanizing and zinc is poisonous when heated, creating deadly fumes. Most plumbing codes, when dealing with gas piping, specify this black "iron".
I worked in a "foundry" during the '70s, a pipe shop. Making pipe from 4 inch to 13 inch. Larger pipe was made in a seperate plant, as was smaller pipe. There are still a few pipe shops operating here. (Birmingham) The pipe is classed as cast iron, but chemically is about the same as cast steel.
It can be welded to, and on. But must be treated ahead of time. And must be cut with a tool that scribes. But cannot be cut with a flame, it must be broken. But it can be bent into a horse shoe shape, under pressure. The QC machine for that is scarey