This will be 220v plug and receptacle
There's a lot of those. The purpose of the different ones are to keep you (or anyone) from plugging devices into an incompatible supply.
Is it the three pin, vertical spade type that looks like a giant version of the standard 120v household receptacle?
If so, (this is so wrong...... But if you're careful and dilligent.....) you're gonna be "stuffing" those wires in there. Before you void the return policy, make sure the bundle of three will fit through it AND clamp securely, AND still close the assemblies. They might fit OK since they're not made into a proper cord. After that, I don't think you'll find any that will accept the 4 gauge wire at the pins. My first thought is that you can (probably.....) find a crimp lug (rated at 50 amps or better) and lock that under the screws that come in the plug/receptacle. Might depend on how the screws are oriented in the assembled position.
But however it works out..... Jankey connections make heat, smoke, and fire faster than undersized wires. Just make sure it's rock solid, proper connections, and it'll work. ("Proper"..... I hope you're taking that in context..... It's an extension cord, OUTSIDE the wall, that you presumably have chain of custody over while it's in use...) Sketchy work in the connections department usually works perfectly, and lasts just long enough to make you start to feel comfortable with it. Watch your details and I'm sure it'll work fine.