Chris of Clickspring fame just dipped his brass parts in a thin lacquer after polishing. Seems like that should be sufficient, though his pieces aren't meant to be handled as much as a top.
I have only used about a dozen colors of powdercoat, but almost half of those were different types of clear. We never found one that preserved the look of the metal underneath. They all looked like plastic (because, of course, that's what powdercoating is). Of course it also depends on how controlled your application is. If you're very good at it, and your machine is set up just right, you could probably do a thin enough cost to minimize that effect, but even with a top of the line Wagner Sprint AirFluid gun and a trainer from Sherwin Williams own powder division I never saw it. Wouldn't bother me at all to learn that it can be done, though.