I've bought sil/phos at HD a couple of times. Good for air conditioning work. Color doesn't match perfectly for cosmetic purposes, but it is strong. Now they make a glue for a/c work good for 1200 psi. Sounds crazy.
I buy ss for welding copper tubing now from the a/c supply house. Pretty high but no flux needed. Just like gas welding.
Copper electrical wire isn't the best for welding copper, but it will work. It can be TIG welded, or O/A. Most welding filler rods are oxy free, but still bare solid wire can be used. Probably never pass code, but for ornamental work, or non-critical applications it's probably just fine.