Thanks for the pointer, Dabbler. OK, so let me know if I've generally got this right. My layman's read of Mr. Google's offerings on anti-seize compounds is --With aluminum/steel, make sure that you have a good fit and use silver anti-seize when assembling. After 30 years they will still come apart easily. (you already know how I know)
Layman's terms : Anti-sieze compound from a reputable source "it works ! "Thanks for the pointer, Dabbler. OK, so let me know if I've generally got this right. My layman's read of Mr. Google's offerings on anti-seize compounds is --
The metallic contents in an anti-seize compound serve as a cathode (steal electrons) or as an anode (give electrons) in a galvanic reaction, depending on the metals in the compound and the metals of the components involved. The reactions result in a thin film of corroded metals on one or possibly multiple mating metal components. The film then acts as an insulating barrier between the the dissimilar metals of the mating parts. The grease aspect of the compound serves as a medium for the suspended metals, and also as a means of preventing entry of electrolytes, such as water moisture, into the mated surfaces.
In this case of an aluminum pulley on an iron (Fe) spindle, the copper (Cu) in "silver" compound is to the right of iron (Fe) on the periodic table. So it reacts as an anode for the iron and also as a cathode for the aluminum (Al). The aluminum bits in the compound are even further to the right from Fe, so it also reacts (as an anode) to the iron (the cathode).
Well, to be a picky beggar --I have a few of these pulleys down the basement headed for the landfill . I'll see what I can come up with .
You can pretty much interfere with the aluminium oxide build-up against the steel shaft by making it "dirty" with "copper-ease" or similar anti-sieze compound. Enough grease in there, and deliberately taking it off occasionally also works.Yes, I'll probably go with the aluminum one I've found. I'm just concerned about galvanic corrosion, from mixing dissimilar metals. The two original pulleys are aluminum, but they're on greased bearings. The pulley for the motor spindle has to be in direct contact, though. (I've already got a couple "examples" of galvanized things in my life now I'd have to destroy to get them apart.)