OK, not too nice looking ...
... but the apparent misalignment might be due to a crummy column mount casting. Before you start cutting metal, do what you can to check that the face of the column is perpendicular to the Y dovetails (or parallel to the table).
That said, note that even if the face of the column is not square to the Y axis or parallel to the X, it won't have
any effect on the accuracy or operation of the machine. Consider a round column mill. The head can rotate around the vertical axis, and does so whenever you raise or lower the head. But once it's locked in place, as long as you can re-establish 0,0, the actual angle is immaterial. Bridgeport mills have rotatable heads, too.
The only thing you have to worry about with your mill is the
tram of the head. The side-to-side tram is of course adjustable with that great big bolt. It'll take some care to adjust, as there may be shifting as the bolt is tightened. Front-to-back adjustments are only possible by dismounting the column and either scraping the castings or adding shims.