Here's what I came up with...
I clamped the part on a big aluminum block with another copper plate butted right up on the underside of the pin. This plate just happened to have a big hole in it the straddled the pin nicely.
To keep pressure upwards on the pin I used a small arced piece of copper plate. It acted like a leaf spring to hold the pin in place.
For the actual welding I swapped the spring clamps for vice grip pliers. I hit it with a MAPP gas torch for a few minutes for a little pre heat then welded around the groove with a 3/32" Hastelloy-W rod. In hindsight I could've used a 1/16" rod probably and the weld would've been a little more concave.
After the weld was laid in I went back over it with a somewhat hotter weave to flatten it out.
I came out pretty flat to slightly concave which is what I was hoping for.
I tried to do a nice tapering out on the finish.
After welding I hit it with a MAPP torch a little bit to help it cool more slowly. It doesn't seem to have warped at all but we'll see when it's unclamped. Fingers crossed!
Thanks for all the advice guys! I guess I won't know if this is a good repair until it's seen some service.