There are a lot of adjustments there. Nice looking vise, BTW. I would set everything to zero and sweep the base with an indicator to square the vise with the ways. What happens next would depend upon your intended use. Assuming the final setup is as you depicted and you trust the accuracy of the scales, you should be good to go. I read the primary angle as 27º 42'. If you are looking for more accuracy for the angle settings, you would have to use a sine bar, angle gage, or other means to verify the angle. Joe Pieczynski did a You Tube video concerning creating custom angle gages a while back. The idea is to use the gage to create a surface parallel to the bed or to one of the ways and sweep it with an indicator to verify the angle. The compound angle settings make this a bit tricky as I would use the vise to hold my gages but it can be done. I would do the primary angle with the secondary angle set at zero and make as accurate a reading on the scale as I could. Then I would set that angle to zero and set the secondary angle to the desired value, mount my gage for that angle and sweep it. Then I would set my primary angle to the corrected setting and you shoyld be good to go. With careful work, you should be able to hit your angles to a minute or two of arc.