I use rosin mostly for electronics. But if I have a broken mount for a board, I will use the acid. I clean it immediately.
I use acid for electrical, heavy stuff. For my F3B winches, I crimped the welding cables with terminal ends (forget what they are called), then used the acid core, and soldered the connection. We want full contact, so that we are not changing resistance. Each winch has to meet a certain resistance, and if the connection is weathering it changes. With ACID and ROSIN I clean all connections afterwards. I use alcohol wipe it clean, and/or flood it.
As long as you clean up both will be safe.
I find old electrical that was soldered, when resoldering, I find the kester Acid to work better at reflowing and resoldering.
I am no expert by the way, it's just what I found that works for me.
edit: btw both were sold by my semi local Electronics house... Greenbrook Electronics. Not a plumbing supply or Home center.