On normal spur gears (lathe change gears, those in your car's gearbox), the pressure angle is easiest to think of like this:
imagine a line between the centres of the two gears (shaft axis), and two teeth meeting so that their contact point is on that line and at their pitch circles. the contact force between the teeth (at 90 degrees to the tooth surface) will be tilted through the pressure angle, usually 14.5 degrees or 20 degrees, and the tooth faces will be tilted through the same angle from the line between the centres.
This leads to "OK, what's the pitch circle?"!
the pitch circle is the diameter of a *roller* meshed with another *roller* to give the required ratio of rotation between the two shafts - given enough friction this will work as well as a gear, but as we don't live in a world with infinite friction we have to add teeth that lock the two rollers together and prevent slip - this is done by giving each tooth an "addendum" that sticks up above the roller surface, and a "dedendum" dug out of the surface for the other "roller"'s tooth addendum to fit into.
In most gears the addendum adds an extra diameter of 2 tooth diametral pitches**, the dedendum subtracts 2 (and a smidge of clearance) - which leads on to...
"What's a diametral pitch?" in the roller example, to work out the ratio we only need to look at the diameter of the two rollers, and we can add them together and take half as the distance between centres - easy peasy
When we add teeth, we need them to mesh correctly, and such is the way of geometry that if we have the same ratio of teeth as we have of pitch diameters, they will (if the right shape) mesh nicely and give the ratio we want - this leads to the gear's diametral pitch, the number of teeth per inch of diameter (or in metric, the gear's module, diameter in mm per tooth). Gears with the same module or diametral pitch number will mesh with each other...
"but you said 'if the right shape' didn't you?" - yep, and there are two classes of gears commonly found - cycloid (mostly in clocks and watches or very old machinery) and involute (almost everything else!) - these have curves which complement each other, the involute curve can be generated by the simple method of unwinding a string from around our roller and marking where fixed points on the string go as we do it - not that gears are made that way
The simplest way of creating an accurate involute is with a gear shaper, which uses a rack as a cutter against a gear blank - the rack is moved along and the gear is rotated in synchrony as the rack is moved back + forth, shaving away the spaces between the teeth - the rolling and linear motions combine to give the "unwinding" motion that creates the involute curve, and the angle of the rack faces sets the pressure angle (e.g 14.5 or 20 degrees), the rack being effectively an infinite tooth gear.
** so a 46-tooth 16 diametral pitch will be 48/16 inches = 3 inches over the tops of the teeth, 44/16 or 2.75 inches (less a little bit for clearance) from dip-to-dip - similar for metric module gears, +2 module and -(2 module and a bit for clearance)
Hope this helps rather than confuses!
Dave H.