The bull gear pin hole has a boss in the original casting to provide some meat. It would be easy to sleeve/bush like francist said above. By sleeving, you are essentially driving the pin with a larger diameter hole, which reduces the pressure per unit area that the pin exerts on the pulley.
I'm not a fan of Zamak, but I do care for a number of Zamak parts. It's a war-economy substitution metal, not a high performance alloy. I don't know where to find engineering specs for that material, but I don't think that 6061 could be much weaker, if at all... is your billet T6 heat treated? The list of products taking daily abuse made of 6061-T6 is really, really long. I have trusted my life to it in vehicles, sports equipment, motorcycles, and more. I can't say the same for Zamak, but my catalog year 1937 lathe is still going, so maybe there's something to that.