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more than likely your issue is polarity
I think your culprit is the mill scale. TIG welding does not play well with the scale.
You could try some 309 or even some 308 S/S wire but plain ole ER70S-2 should work fine as long as the metal is bare and clean. I am not a fan of using S/S wire to mask an underlying issue, I use it where the weld or specs call for it.
Mike.